Nickamine
Reagent used as a catalyst for cross-coupling reactions between alkyl halides and carbon nucleophiles. Catalyst for alkyl-alkyl Kumada coupling of secondary alkyl halides, direct alkylation of heterocyclic C-H bonds, Sonogashira coupling of nonactivated alkyl halides, Kumada-Corriu-Tamao coupling of nonactivated alkyl halides with aryl and heteroaryl nucleophiles. Reactant of pincer NN2 ligand leading to selective carbon-carbon bond formation.
Catalog Number | CDX-B0150-M500 |
Alternative Name(s) | Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride; Chloro[N2-[2-(dimethylamino-kappaN)phenyl]-N1,N1-dimethyl-1,2-benzenediaminato-kappaN1,kappaN2]-nickel |
Research Area | Biochemicals, Immunology |
Molecular Formula | C16H20ClN3Ni |
CAS# | 1033772-47-2 |
Purity | >97% |
Inchi | InChI=1S/C16H20N3.ClH.Ni/c1-18(2)15-11-7-5-9-13(15)17-14-10-6-8-12-16(14)19(3)4;;/h5-12H,1-4H3;1H;/q-1;;+2/p-1 |
Inchi Key | IRLHVNUEEKJBEL-UHFFFAOYSA-M |
SMILES | C[N]1(C)C2=CC=CC=C2N2C3=C(C=CC=C3)[N](C)(C)[Ni]12Cl |
Size | 500 mg |
Supplier Page | http://www.adipogen.com/cdx-b0150/nickamine.html |