(11bS)-2,6-Diphenyl-N,N-bis(1-phenylethyl)dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

(11bS)-4-[(1R,2R)-2-(1,3-Dihydro-2H-isoindol-2-yl)-1,2-diphenylethyl]-4,5-dihydro-3H-dinaphth[2,1-c:1′,2′-e]azepine is a chiral catalyst that has been intensively applied in asymmetric reactions with high atom economy.

(11bS)-4-Hydroxy-2,6-bis([1,1′:3′,1”-terphenyl]-5′-yl)-4-oxide-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin is a chiral phosphoric acid catalyst for a variety of enantioselective transformations, especially for carbon-carbon and carbon-heteroatom bond-forming reactions.

(11bS)-4-Hydroxy-2,6-bis(2,3,4,5,6-pentafluorophenyl)-4-oxide-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin is a chiral phosphoric acid catalyst for a variety of enantioselective transformations, especially for carbon-carbon and carbon-heteroatom bond-forming reactions.

(11bS)-4-Hydroxy-2,6-bis(2,4,6-tricyclohexylphenyl)-4-oxide-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin is a chiral phosphoric acid catalyst for a variety of enantioselective transformations, especially for carbon-carbon and carbon-heteroatom bond-forming reactions.