(11bR,11’bR)-4,4′-(1S,2S)-1,2-Cyclohexanediylbis[4,5-dihydro-3H-dinaphth[2,1-c:1′,2′-e]azepine] is a chiral catalyst that has been intensively applied in asymmetric reactions with high atom economy.

(11bR,11’bR)-4,4′-[(1S,2S)-1,2-Diphenyl-1,2-ethanediyl]bis[4,5-dihydro-3H-dinaphth[2,1-c:1′,2′-e]azepine] is a chiral nitrogen ligand for enantioselective synthesis.

(11bR)-1-(2-(3H-Dinaphtho[2,1-c:1′,2′-e]azepin-4(5H)-yl)-1,2-diphenylethyl)-3-(3,5-bis(trifluoromethyl)phenyl)thiourea is a chiral thiourea catalyst that has emerged as an efficient class of organocatalysts due to their unique dual hydrogen-bonding capacity.

As a strong chiral Brønsted acid, (11bR)-1,1,1-Trifluoro-N-(4-oxido-2,6-di(phenanthren-9-yl)-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl)methanesulfonamide is a chiral N-triflyl phosphoramides organocatalysts for enantioselective synthesis.

(11bR)-2,2′-(Oxybis(methylene))bis(N,N-dimethyldinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine) is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.