tert-Butyldimethylsilyl cyanide
tert-Butyldimethylsilyl cyanide (TBDMSCN) is a bulkier trialkylsilylcyanide. It participates in the cyanosilylation of enantiopure 4-oxoazetidine-2-carbaldehydes. Addition of TBDMSCN to sterically hindered ketones in the presence of Lewis acid or base catalyst has been studied. ZnI2-catalyzed addition of TBDSCN to 2,2-dimethylcyclohexanone, 2,2,6-trimethylcyclohexanone and 2,2,6,6-tetramethylcyclohexanone affords protected cyanohydrins.
| Catalog Number | CBB1118746 |
| Alternative Name(s) | tert-Butyl-cyano-dimethylsilane |
| Molecular Formula | (CH3)3CSi(CH3)2CN |
| CAS# | 56522-24-8 |
| Purity | >97% |
| Inchi | 1S/C7H15NSi/c1-7(2,3)9(4,5)6-8/h1-5H3 |
| Inchi Key | CWAKIXKDPQTVTA-UHFFFAOYSA-N |
| SMILES | CC(C)(C)[Si](C)(C)C#N |
| Size | Inquiry |
| Supplier Page | https://www.amerigoscientific.com/tert-butyldimethylsilyl-cyanide-item-118746.html |