9-Phenyl-9-fluorenol is a fluorine derivative. It is formed as intermediate during the synthesis of 9-bromo-9-phenylfluorene. Competitive interactions in crystalline 9-phenyl-9-fluorenol has been reported. Spectral properties of 9-phenyl-9-fluorenol have been investigated. 9-Phenyl-9-fluorenol is reported as bichromphoric fluorine derivative and its absorption and emission characteristics have been investigated in non-polar and polar solvents at different temperatures.