Dichlorotriphenylphosphorane
Dichlorotriphenylphosphorane (Triphenylphosphine dichloride, PPh3Cl2) is a phosphorous halide. Stability and reactivity of dichlorotriphenylphosphorane have been studied by solid state 31P NMR spectroscopy. It participates in the conversion of carboxylic esters to acid halides and mechanism of this cleavage has been investigated. Modified method has been proposed in which dichlorotriphenylphosphorane participates in the synthesis of tertiary amides.
| Catalog Number | CBB1112859 |
| Alternative Name(s) | Triphenylphosphine dichloride |
| Molecular Formula | (C6H5)3PCl2 |
| CAS# | 2526-64-9 |
| Purity | >95% |
| Inchi | 1S/C18H15Cl2P/c19-21(20,16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H |
| Inchi Key | ASWXNYNXAOQCCD-UHFFFAOYSA-N |
| SMILES | ClP(Cl)(c1ccccc1)(c2ccccc2)c3ccccc3 |
| Size | Inquiry |
| Supplier Page | https://www.amerigoscientific.com/dichlorotriphenylphosphorane-item-112859.html |