2-(Trimethylsilyl)-1,3-dithiane
2-(Trimethylsilyl)-1,3-dithiane participates in Lewis base-catalyzed 1,3-dithiane addition to electrophiles such as carbonyl compounds and N-substituted aldimines. It undergoes novel diazo transfer reaction with tosyl azide in hexamethylphosphoramide-THF to yield 2-diazo-1,3-dithiane, which on decomposition yields formal carbene adducts. It is a versatile acyl anion equivalent.
| Catalog Number | CBB1118923 |
| Molecular Formula | C7H16S2Si |
| CAS# | 13411-42-2 |
| Purity | >99% |
| Inchi | 1S/C7H16S2Si/c1-10(2,3)7-8-5-4-6-9-7/h7H,4-6H2,1-3H3 |
| Inchi Key | BTTUMVHWIAXYPJ-UHFFFAOYSA-N |
| SMILES | C[Si](C)(C)C1SCCCS1 |
| Size | Inquiry |
| Supplier Page | https://www.amerigoscientific.com/2-trimethylsilyl-13-dithiane-item-118923.html |