Amerigo Scientific
Methyl pyruvate is a pyruvic ester. Surface conditions during Pt/silica EUROPT-1 modified by cinchonidine catalyzed by enantioselective hydrogenation of methyl pyruvate to R-(+)-methyl lactate were investigated. Enantioselective hydrogenation of methyl pyruvate over finely dispersed polyvinylpyrrolidone-stabilized and the corresponding alumina-supported iridium clusters modified with cinchonidine was studied. The molecular orientation and conformation of methyl pyruvate on […]
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Amerigo Scientific
Thiazolidine-2-carboxylic acid methyl ester hydrochloride is a cyclic secondary amino acid derivative. The thiazolidine-2-carboxylic acid (Thz) moiety can exhibit ACE (angiotensin converting enzyme) inhibitor activity in vivo.
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Amerigo Scientific
Methyl thioglycolate reacts with nonprotein component of the antitumor antibiotic neocarzinostatin to form 1:1 adduct. It reacts with isothiocyanate to form Rhodanine.
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Amerigo Scientific
Amerigo Scientific
Methyl trans-2-methyl-2-pentenoate is an α,β-unsaturated ester. It is formed during the photolysis of pyrazoline. Methyl cis- and trans-2-methyl-2-pentenoate are formed during the pyrolysis of cis- and trans-3,5-dimethyl-3-carbomethoxy-Δ1-pyrazoline.
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Amerigo Scientific
Methyl trans-3-pentenoate is an ester. Ring-closing metathesis (RCM) of methyl trans-3-pentenoate using silica- and monolith supported Grubbs-Herrmann-type catalysts has been reported. The 1,3-dipolar cycloaddition of with C-ethoxycarbonyl nitrone to form isoxazolidines has been studied.
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Amerigo Scientific
Amerigo Scientific
Methyl trifluoroacetate along with cesium fluoride or cesium chloride and CuI constitutes a valuable trifluoromethylating reagent for substituting aromatic (or heteroaromatic) iodides and bromides. Adsorption of methyl trifluoroacetate on amorphous silica has been investigated. Fragmentation mechanism of generation of metastable ions from methyl trifluoroacetate has been investigated by mass analyzed ion kinetic energy spectra and […]
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Amerigo Scientific
Methyl trimethylsilylacetate on reaction with lithium diisopropylamide in THF at -78°C yields methyl lithiotrimethylsilylacetate. It also undergoes Peterson olefination to yield mainly Z-isomers of steroid 17β-side chain methyl acrylates.
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Amerigo Scientific
Methyl valerate is a methyl ester of valeric acid, generally used as a fragrance in the manufacture of soaps and laundry detergents. It is also used as a plasticizer and surrogate component for?biodiesel.
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Amerigo Scientific
Amerigo Scientific
Methyl α-bromophenylacetate is an ester. Palladium catalyzed homocoupling reaction of methyl α-bromophenylacetate with 3,5-dimethyl phenyl boronic acid is reported.
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