(tert-Butyldimethylsilyl)acetylene

(tert-Butyldimethylsilyl)acetylene is a bulky trialkylsilyl-protected alkyne. It participates in Cadiot-Chodkiewicz cross-coupling reaction with various bromoalkynes to afford synthetically useful unsymmetrical diynes. (tert-Butyldimethylsilyl)acetylene readily undergoes cross-dimerization reaction with various internal phenyl acetylenes in the presence of rhodium dimers and bidentate phosphine ligands to afford enynes.

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Catalog Number	CBB1115881
Alternative Name(s)	Ethynyl-tert-butyldimethylsilane
Molecular Formula	(CH3)3CSi(CH3)2C≡CH
CAS#	86318-61-8
Purity	>99%
Inchi	1S/C8H16Si/c1-7-9(5,6)8(2,3)4/h1H,2-6H3
Inchi Key	RTYNRTUKJVYEIE-UHFFFAOYSA-N
SMILES	CC(C)(C)[Si](C)(C)C#C
Size	Inquiry
Supplier Page	https://www.amerigoscientific.com/tert-butyldimethylsilylacetylene-item-115881.html