Ethyl potassium malonate

Ethyl potassium malonate (potassium ethyl malonate) reacts with aryl nitriles in the presence of zinc chloride and a catalytic amount of Hünig′s base to yield β-amino acrylates. Ethyl potassium malonate is formed as an intermediate during the synthesis of ethyl tert-butyl malonate.

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Catalog Number CBB1114562
Alternative Name(s) Monoethyl malonate potassium salt; Potassium monoethyl malonate
Molecular Formula C2H5OCOCH2CO2K
CAS# 6148-64-7
Purity >98%
Inchi 1S/C5H8O4.K/c1-2-9-5(8)3-4(6)7;/h2-3H2,1H3,(H,6,7);/q;+1/p-1
Inchi Key WVUCPRGADMCTBN-UHFFFAOYSA-M
SMILES [K+].CCOC(=O)CC([O-])=O
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